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There are strong demands today to further improve the thermal efficiency of internal combustion engines against a backdrop of various environmental issues, including rising carbon dioxide (CO2) emissions and global warming. One factor that impedes efforts to improve the thermal efficiency of spark ignition engines is the occurrence of knocking. The aim of this study was to elucidate the details of knocking based on spectroscopic measurements and visualization of phenomena in the combustion chamber of a test engine that was operated on three primary reference fuels with different octane ratings (0 RON, 30 RON, and 50 RON). The ignition timing was retarded in the experiments to delay the progress of flame propagation, making it easier to capture the behavior of low-temperature oxidation reactions at the time knocking occurred.

This study attempted to elucidate combustion conditions in a progression from normal combustion to knocking by analyzing the ion current and light emission intensity that occurred during this transition. With the aim of understanding the combustion states involved, the ion current was measured at two positions in the combustion chamber. Light emission spectroscopy was applied to examine preflame reactions that are observed prior to autoignition in the combustion process of hydrocarbon fuels. The results obtained by analyzing the experimental data made clear the relationship between the ion current and light emission during the transition from normal combustion to knocking operation.

A new concept of combustion which is using the characteristic of plasma jet ignition, that is the plasma jet diffusive combustion is proposed. The constant volume vessel is used for the experiment, and methanol is charged in the cavity of plasma jet injector and the air at room temperature and atmospheric pressure is charged in the combustion chamber. The combustion characteristic is analyzed by measuring the combustion pressure and visualization of the combustion process. The plasma jet injector configuration and the ratio of methanol volume to cavity volume influence not only the plasma jet diffusive combustion process but also the maximum combustion pressure. In cases of small orifice diameter, the plasma jet diffusive combustion is not recognized, and the maximum combustion pressure increases as the orifice area becomes large.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition in the combustion reaction process of hydrocarbon fuels. Attention was focused on light emission behavior at wavelengths corresponding to those of formaldehyde (HCHO), Vaidya's hydrocarbon flame band (HCO) and the OH radical in a forced progression from normal combustion to a knocking state. Light emission behavior was measured simultaneously in the center and in the end zone of the combustion chamber when the engine was operated on two different test fuels. The test fuels used were n-heptane (0 RON) and a blended fuel (70 RON) consisting of n-heptane (0 RON) and iso-octane (100 RON).

In-cylinder visualization of the entire bore area at an identical frame rate was used to investigate knocking conditions under spark ignition (SI) combustion and under Homogeneous Charge Compression Ignition (HCCI) combustion in the same test engine. A frequency analysis was also conducted on the measured pressure signals. The results revealed that a combustion regime accompanied by strong pressure oscillations occurred in both the SI and HCCI modes, which was presumably caused by rapid autoignition with attendant brilliant light emission that took place near the cylinder wall. It was found that the knocking timing was the dominant factor of this combustion regime accompanied by cylinder pressure oscillations in both the SI and HCCI combustion modes.

Improving the thermal efficiency of internal combustion engines requires operation under a lean combustion regime and a higher compression ratio, which means that the causes of autoignition and pressure oscillations in this operating region must be made clear. However, there is limited knowledge of autoignition behavior under lean combustion conditions. Therefore, in this study, experiments were conducted in which the ignition timing and intake air temperature (scavenging temperature) of a 2-stroke optically accessible test engine were varied to induce autoignition under a variety of conditions. The test fuel used was a primary reference fuel with an octane rating of 90. The results revealed that advancing the ignition timing under lean combustion conditions also advanced the autoignition timing, though strong pressure oscillations on the other hand tended not to occur.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest as a combustion system that offers the advantages of high efficiency and low exhaust emissions. However, it is difficult to control the ignition timing in an HCCI combustion system owing to the lack of a physical means of initiating ignition like the spark plug in a gasoline engine or fuel injection in a diesel engine. Moreover, because the mixture ignites simultaneously at multiple locations in the cylinder, it produces an enormous amount of heat in a short period of time, which causes greater engine noise, abnormal combustion and other problems in the high load region. The purpose of this study was to expand the region of stable HCCI engine operation by finding a solution to these issues of HCCI combustion.

Technologies for further improving vehicle fuel economy have attracted widespread attention in recent years. However, one problem with some approaches is the occurrence of abnormal combustion such as low-speed pre-ignition (LSPI) that occurs under low-speed, high-load operating conditions. One proposed cause of LSPI is that oil droplets diluted by the fuel enter the combustion chamber and become a source of ignition. Another proposed cause is that deposits peel off and become a source of ignition. A four-stroke air-cooled single-cylinder engine was used in this study to investigate the influence of Ca-based additives having different properties on abnormal combustion by means of in-cylinder visualization and absorption spectroscopic measurements. The results obtained for neutral and basic Ca-based additives revealed that the former had an effect on advancing the time of autoignition.

Issues that must be addressed to make Homogeneous Charge Compression Ignition (HCCI) engines a practical reality include the difficulty of controlling the ignition timing and suppression of rapid combustion under high load conditions. Overcoming these issues to make HCCI engines viable for practical application is indispensable to the further advancement of internal combustion engines. Previous studies have reported that the operating region of HCCI combustion can be expanded by using DME and Methane blended fuels.(1), (2), (3), (4), (5) The reason is that the reaction characteristics of these two low-carbon fuels, which have different ignition properties, have the effect of inducing heat release in two stages during main combustion, thus avoiding excessively rapid combustion. However, further moderation of rapid combustion in high-load region is needed to expand the operation region. This study focused on supercharging and use of blended fuels.

This study was conducted to investigate the influence of cooled recirculated exhaust gas (EGR) on abnormal combustion in a Homogenous Charge Compression Ignition (HCCI) engine. The condition of abnormal HCCI combustion accompanied by cylinder pressure oscillations was photographed with a high-speed camera using a 2-stroke optically accessible engine that enabled visualization of the entire bore area. Exhaust gas was cooled with a water-cooled intercooler for introducing cooled EGR. Experiments were conducted in which the quantity of cooled EGR introduced was varied and a comparison was made of the autoignition behavior obtained under each condition in order to investigate the influence of cooled EGR on abnormal HCCI combustion. The results revealed that cylinder pressure oscillations were reduced when cooled EGR was introduced. That reduction was found to be mainly ascribable to the effect of cooled EGR on changing the ignition timing.

The purpose of this study is to clarify ignition characteristics and engine performance of FAME for 4-stroke diesel engine in low compression ratios. Diesel fuel and coconut oil methyl ester (CME) were selected as test fuels, because CME consisted of saturate FAMEs which were good ignition characteristics. To reduce the compression ratio, thin copperplates were inserted between cylinder head and cylinder block and the compression ratio was reduced from 20.6 that was standard to 15. The engine starting test and an ordinary engine performance test were made at 3600 min.-₁. In engine starting test, the engine was soaked at room temperature and the ignition timing of diesel fuel was remarkably delayed compared with CME. When the compression ratio was 16, for diesel fuel, the misfiring cycles were included during engine warming up. In case of 15 of compression ratio, the engine could not be started by diesel fuel; however the engine could be run by CME.

With the aim of elucidating the mechanism generating knock, an examination was made of the preflame reaction behavior of end gas in the combustion chamber in the transition from normal combustion to abnormal combustion characterized by the occurrence of knocking. Simultaneous measurements were made in the same cycle of the light absorption and emission behavior of the OH (characteristic spectrum of 306.4 nm), CH (431.5 nm) and C2 (516.5 nm) radicals in the end-gas region using spectroscopic methods. The absorbance behavior of a blue flame prior to autoignition is believed to be an important factor in the mechanism causing knock.

Using absorption spectroscopy, simultaneous measurements were made of the behavior of the OH (characteristic spectrum of 306.4 nm), CH (431.5 nm) and C2(516.5 nm) radicals in the end-gas region and center of the combustion chamber of a spark-ignition engine during preflame reactions with four types of fuel having different octane numbers. The results of this research show that the behavior of the OH, CH and C2 radicals in preflame reactions differed significantly in both the center and end-gas region of the combustion chamber depending on the octane number of the fuel and also between normal and knocking combustion conditions.

Emission intensity was measured at a wavelength of 395 2 nm (corresponding to the characteristic spectrum of the HCHO radical) and absorbance was measured at 306 4 nm (corresponding to that of the OH radical). The emission intensity and absorbance waveforms recorded during engine operation on n-heptane show behavior indicative of the passage and degeneracy of cool flame in the preflame reaction interval. As the combustion chamber wall temperature approached an overheated state in the transition from normal combustion to knocking operation different preflame reaction behavior was observed which is thought to correspond to the presence of a negative temperature coefficient region related to the ignition delay time.

Homogenous Charge Compression Ignition (HCCI) combustion experiments were conducted in this study using a single-cylinder test engine fitted with a sapphire observation window to facilitate visualization of the entire cylinder bore area. In addition to in-cylinder visualization of combustion, spectroscopic measurements were made of light emission and absorption in the combustion chamber to investigate autoignition behavior in detail. Engine firing experiments were conducted to visualize HCCI combustion over a wide range of compression ratios from 12:1 to 22:1. The results showed that increasing the compression ratio advanced the ignition timing and increased the maximum pressure rise rate, making it necessary to moderate combustion. It was also found that autoignition can be induced even in a mixture lean enough to cause misfiring by raising the intake air temperature so as to advance the overall combustion process.

This study examined Homogeneous Charge Compression Ignition (HCCI) combustion characteristics in detail on the basis of in-cylinder combustion visualization, spectroscopic measurements of light emission and absorption and chemical kinetic simulations. Special attention was focused on investigating and comparing the effects of the fuel octane number and residual gas on combustion characteristics. The results made clear the relationship between the production/consumption of formaldehyde (HCHO) in the HCCI autoignition process and flame development behavior in the cylinder. Additionally, it was found that both the fuel octane number and residual gas have the effect of moderating low-temperature oxidation reactions. Furthermore, it was observed that residual gas has the effect of shifting the temperature for the occurrence of the hot flame to a higher temperature range.

The growing severity of global environmental issues in recent years, including air pollution and the depletion of fossil fuels, has made it necessary for internal combustion engines to achieve higher efficiency and lower exhaust emission levels. Calls for reducing atmospheric emissions of carbon dioxide (CO₂) necessitate thoroughgoing measures to lower the levels of CO₂ originating in the combustion process of internal combustion engines and to facilitate operation on diverse energy sources. Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest because it achieves high efficiency and can reduce particulate matter (PM) and nitrogen oxide (NOx) emissions simultaneously. These characteristics are obtainable because HCCI combustion can take place at ultra-lean conditions exceeding the limits of flame propagation.

Controlled Autoignition (CAI) combustion processes can be broadly divided between a CAI process that is applied to four-stroke engines and a CAI process that is applied to two-stroke engines. The former process is generally referred to as Homogeneous Charge Compression Ignition (HCCI) combustion and the later process as Active Thermo-Atmosphere Combustion (ATAC). The region of stable engine operation differs greatly between these two processes, and it is thought that the elucidation of their differences and similarities could provide useful information for expanding the operation region of HCCI combustion. In this research, the same two-stroke engine was operated under both the ATAC and HCCI combustion processes to compare their respective combustion characteristics. The results indicated that the ignition timing was less likely to change in the ATAC process in relation to changes in the fuel octane number than it was in the HCCI combustion process.

In this study, a spectroscopic method was used to measure the combustion characteristics of a test diesel engine when operated on dimethyl ether (DME) under a homogenous charge compression ignition (HCCI) combustion process. A numerical analysis was made of the elementary reactions using Chemkin 4.0 to perform the calculations. The results of the analysis showed that compression ratio changes and the methane additive influenced the autoignition timing in the DME-HCCI combustion process. In the experiments, reducing the compression ratio delayed the time of the peak cylinder pressure until after top dead center, thereby increasing the crankshaft output and thermal efficiency. The addition of methane enabled the DME-HCCI engine to provide crankshaft output equivalent to that seen for diesel engine operation at a low equivalence ratio. This paper discusses these effects in reference to the experimental and calculated results.

In this research, an investigation was made of ion current and OH radical luminescence behavior in the progression from normal combustion to knocking operation. One pair each of an ion probe and a quartz observation window was fitted in the center and on the end of the combustion chamber. The peak values of the ion voltage drop and the OH radical emission intensity both increased as the cylinder head temperature and the cylinder pressure rose. It is possible to understand combustion conditions by analyzing measured waveformes of the ion voltage drop and the OH radical emission intensity.